Alcohol-promoted ring-opening alkyne metathesis polymerization.
نویسندگان
چکیده
Alcohol is the answer! An inactive, air-stable, dimeric molybdenum alkylidyne complex is activated toward ring-opening alkyne metathesis polymerization (ROAMP) by the addition of methanol. The ROAMP is compatible with water and phenol-containing substrates and with the in situ photochemical generation of alkyne monomers from cyclopropenones.
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ورودعنوان ژورنال:
- Angewandte Chemie
دوره 52 17 شماره
صفحات -
تاریخ انتشار 2013